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Simulation analysis of methanol flash distillation circulation process in biodiesel production with supercritical

Zhengjiao TANG, Cunwen WANG, Weiguo WANG, Jia GUO, Yuanxin WU, Jinfang CHEN, Yigang DING

《能源前沿（英文）》 2011年 第5卷 第1期   页码 93-97 doi: 10.1007/s11708-010-0028-7

摘要： High methanol-to-oil ratio is required to obtain a high conversion of oil for the production of biodiesel with supercritical methanol. Recovering the methanol of a stream issuing from a transesterification supercritical reactor by flash distillation instead of evaporation was analyzed. The one-stage and two-stage flash distillation processes were presented and compared. The difference of the recovery percentage of methanol of the above two flash processes is less than 0.5% and the methanol concentration in the vapor for the one-stage process decreases rapidly when feed temperature increases. The process in which the product of transesterification of soybean oil with supercritical methanol is cooled to an appropriate temperature (about 240°C) first and then flashed was put forward. The effect of cooling temperature, feed pressure and flash pressure on methanol concentration and recovery percentage was investigated. According to this study, when the feed pressure range is 15–30 MPa, the flash pressure equals 0.4 MPa, and cooling temperature range is 240°C–250°C, the recovery percentage of methanol is not less than 85%, and the concentration of the vapor in mass fraction of methanol is approximately 99%. Thus, the vapor leaving the flash tank can be directly circulated to the transesterification reactor.

关键词： supercritical methanol     biodiesel     recovery     flash distillation    

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A novel method for generating distillation configurations

Hongzhe Hou, Yiqing Luo

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 834-846 doi: 10.1007/s11705-019-1855-7

摘要： An improved matrix method for generating distillation configurations with ( −1) and less than ( −1) columns was proposed for the separation of an -component mixture into essentially pure product streams based on the concepts of streams matrix and 0–1 matrixes proposed by Agrawal. In contrast with the matrix method developed by Agrawal, the present method removes the intermediate process centered on the splits, and complex column configurations, allowing the direct generation of multi-feeds and multi-product streams. Furthermore, certain configurations that cannot be generated directly and that are missing in the matrix method are obtained. Through rigorous simulations and optimization, we have demonstrated that these configurations have the potential to outperform certain existing configurations.

关键词： non-sharp separation     multicomponent distillation     distillation configurations    

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Phase change effect of low melting point metal for an automatic cooling of USB flash memory

Haoshan GE, Jing LIU

《能源前沿（英文）》 2012年 第6卷 第3期   页码 207-209 doi: 10.1007/s11708-012-0204-z

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Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation

Kai Wang, Jinbo Pang, Liwei Li, Shengzhe Zhou, Yuhao Li, Tiezhu Zhang

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 376-382 doi: 10.1007/s11705-018-1705-z

摘要：

Carbon nanotubes/graphene composites have superior mechanical, electrical and electrochemistry properties with carbon nanotubes as a hydrophobicity boosting agent. Their extraordinary hydrophobic performance is highly suitable for electrode applications in lithium ion batteries and supercapacitors which often employ organic electrolytes. Also the hydrophobic features enable the oil enrichment for the crude oil separation from seawater. The ever reported synthesis routes towards such a composite either involve complicated multi-step reactions, e.g., chemical vapor depositions, or lead to insufficient extrusion of carbon nanotubes in the chemical reductions of graphene oxide, e.g., fully embedding between the compact graphene oxide sheets. As a consequence, the formation of standalone carbon nanotubes over graphene sheets remains of high interests. Herein we use the facile flash light irradiation method to induce the reduction of graphene oxides in the presence of carbon nanotubes. Photographs, micrographs, X-ray diffraction, infrared spectroscopy and thermogravimetric analysis all indicate that graphene oxides has been reduced. And the contact angle tests confirm the excellent hydrophobic performances of the synthesized carbon nanotube/reduced graphene oxide composite films. This one-step treatment represents a straightforward and high efficiency way for the reduction of carbon nanotubes/graphene oxides composites.

关键词： carbon nanotubes     graphene composite     flash irradiation method     reduced graphene oxide     contact angles    

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A review on membrane distillation in process engineering: design and exergy equations, materials and

《化学科学与工程前沿（英文）》 2022年 第16卷 第5期   页码 592-613 doi: 10.1007/s11705-021-2105-3

摘要： One of the problems that most afflicts humanity is the lack of clean water. Water stress, which is the pressure on the quantity and quality of water resources, exists in many places throughout the World. Desalination represents a valid solution to the scarcity of fresh water and several technologies are already well applied and successful (such as reverse osmosis), producing about 100 million m3·d−1 of fresh water. Further advances in the field of desalination can be provided by innovative processes such as membrane distillation. The latter is of particular interest for the treatment of waste currents from conventional desalination processes (for example the retentate of reverse osmosis) as it allows to desalt highly concentrated currents as it is not limited by concentration polarization phenomena. New perspectives have enhanced research activities and allowed a deeper understanding of mass and heat transport phenomena, membrane wetting, polarization phenomena and have encouraged the use of materials particularly suitable for membrane distillation applications. This work summarizes recent developments in the field of membrane distillation, studies for module length optimization, commercial membrane modules developed, recent patents and advancement of membrane material.

关键词： membrane distillation     recent developments     heat and mass transfer     wetting     membrane material    

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The use of carbon nanomaterials in membrane distillation membranes: a review

Sebastian Leaper, Ahmed Abdel-Karim, Patricia Gorgojo

《化学科学与工程前沿（英文）》 2021年 第15卷 第4期   页码 755-774 doi: 10.1007/s11705-020-1993-y

摘要： Membrane distillation (MD) is a thermal-based separation technique with the potential to treat a wide range of water types for various applications and industries. Certain challenges remain however, which prevent it from becoming commercially widespread including moderate permeate flux, decline in separation performance over time due to pore wetting and high thermal energy requirements. Nevertheless, its attractive characteristics such as high rejection (ca. 100%) of non-volatile species, its ability to treat highly saline solutions under low operating pressures (typically atmospheric) as well as its ability to operate at low temperatures, enabling waste-heat integration, continue to drive research interests globally. Of particular interest is the class of carbon-based nanomaterials which includes graphene and carbon nanotubes, whose wide range of properties have been exploited in an attempt to overcome the technical challenges that MD faces. These low dimensional materials exhibit properties such as high specific surface area, high strength, tuneable hydrophobicity, enhanced vapour transport, high thermal and electrical conductivity and others. Their use in MD has resulted in improved membrane performance characteristics like increased permeability and reduced fouling propensity. They have also enabled novel membrane capabilities such as fouling detection and localised heat generation. In this review we provide a brief introduction to MD and describe key membrane characteristics and fabrication methods. We then give an account of the various uses of carbon nanomaterials for MD applications, focussing on polymeric membrane systems. Future research directions based on the findings are also suggested.

关键词： carbon nanomaterials     graphene     membrane distillation     desalination     carbon nanotubes    

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Design and optimization of reactive distillation: a review

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 799-818 doi: 10.1007/s11705-021-2128-9

摘要： Reactive distillation process, a representative process intensification technology, has been widely applied in the chemical industry. However, due to the strong interaction between reaction and separation, the extension of reactive distillation technology is restricted by the difficulties in process analysis and design. To overcome this problem, the design and optimization of reactive distillation have been widely studied and illustrated for plenty of reactive mixtures over the past three decades. These design and optimization methods of the reactive distillation process are classified into three categories: graphical, optimization-based, and evolutionary/heuristic methods. The primary objective of this article is to provide an up-to-date review of the existing design and optimization methods. Desired and output information, advantages and limitations of each method are stated, the modification and development for original methodologies are also reviewed. Perspectives on future research on the design and optimization of reactive distillation method are proposed for further research.

关键词： reactive distillation     process intensification     design method     reactive phase diagram     optimization algorithm    

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闪速熔炼——清洁高效的炼铜工艺

周松林

《中国工程科学》 2001年 第3卷 第10期   页码 86-89

摘要：

闪速熔炼是当今铜冶金中最具有竞争力的熔炼技术，被认为是标准的清洁炼铜工艺。目前，全球粗铜产量的50%是采用该技术生产的。由于闪速熔炼符合可持续发展战略，世界上大部分新建或改扩建的铜企业均选择该工艺。文章就铜闪速熔炼的特点及发展，阐述了我国铜冶金的现状，提出了我国铜冶金的主要发展方向。

关键词： 闪速熔炼     铜冶金     环保     清洁生产    

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Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects

Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl

《化学科学与工程前沿（英文）》 2018年 第12卷 第4期   页码 670-682 doi: 10.1007/s11705-018-1769-9

摘要：

Methyl acetate is considered low toxicity volatile solvent produced either as a by-product during methanol carbonylation or via acetic acid esterification with methanol. In both cases, pure methyl acetate has to be isolated from the reaction mixture. Simulation of methyl acetate separation from its mixture with methanol by extraction distillation was carried out in ASPEN+ software. In total three case studies were assumed using two different extraction solvents and two solvent regeneration strategies. In case A, novel extraction solvent 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid, was considered. Raw material separation was achieved in an extraction distillation column while the solvent regeneration was accomplished in a second distillation column in this case. In case study B, the same extraction solvent was used; however, its regeneration was carried out in a single-effect evaporator. Dimethyl sulfoxide was the second extraction solvent selected. Its use in methyl acetate-methanol separation is presented in case study C. As high purity of dimethyl sulfoxide was required for the methyl acetate-methanol azeotrope breaking, its regeneration was carried out in the second distillation column only. To simulate the ternary methyl acetate–methanol–extraction solvent mixtures separation, vapor–liquid equilibrium was predicted based on the NRTL equation. Further, unknown properties of the considered ionic liquid and variation of these properties with temperature were predicted and introduced into the ASPEN+ components properties database. Based on these data, optimum operation parameters of the respective separation equipment were established. In all case studies, the same condition had to be fulfilled, namely minimum methyl acetate content in the distillate from the extraction distillation column of 99.5mol-%. Results of simulations using the respective optimum operation parameters were employed in the economic evaluation of the three separation unit designs studied. It was found that the least energy-demanding design corresponds to the case study B in terms of both capital as well as operation expenses.

关键词： methyl acetate     1-ethyl-3-methylimidazolium trifluoromethanesulfonate     extraction distillation     dimethyl sulfoxide     economic evaluation    

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CFD simulation on membrane distillation of NaCl solution

Zhaoguang XU, Yanqiu PAN, Yalan YU

《化学科学与工程前沿（英文）》 2009年 第3卷 第3期   页码 293-297 doi: 10.1007/s11705-009-0204-7

摘要： A computational fluid dynamics (CFD) simulation that coupled an established heat and mass transfer model was carried out for the air-gap membrane distillation (AGMD) of NaCl solution to predict mass and heat behaviors of the process. The effects of temperature and flowrate on fluxes were first simulated and compared with available experimental data to verify the approach. The profiles of temperature, temperature polarization factor, and mass flux adjacent to the tubular carbon membrane surface were then examined under different feed Reynolds number in the computational domain. Results show that the temperature polarization phenomena can be reduced, and mass flux can be enhanced with increase in the feed Reynolds number.

关键词： membrane distillation     computational fluid dynamics (CFD) simulation     temperature polarization     carbon membrane    

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Prediction of the flash points of alkanes by group bond contribution method using artificial neural networks

PAN Yong, JIANG Juncheng, WANG Zhirong

《化学科学与工程前沿（英文）》 2007年 第1卷 第4期   页码 390-394 doi: 10.1007/s11705-007-0071-z

摘要： A group bond contribution model using artificial neural networks, which had the high ability of nonlinear of prediction, was established to predict the flash points of alkanes. This model contained not only the information of group property but also connectivity in molecules. A set of 16 group bonds were used as input parameters of neural networks to study the correlation of molecular structures with flash points of 44 alkanes. The results showed that the predicted flash points were in good agreement with the experimental data that the absolute mean absolute error was 6.9 K and the absolute mean relative error was 2.29%, which were superior to those of traditional group contribution methods. The method can be used not only to reveal the quantitative correlation between flash points and molecular structures of alkanes but also to predict the flash points of organic compounds for chemical engineering.

关键词： information     nonlinear     quantitative correlation     superior     molecular    

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Systematic screening procedure and innovative energy-saving design for ionic liquid-based extractive distillation

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 34-45 doi: 10.1007/s11705-022-2234-3

摘要： In the traditional extractive distillation process, organic solvents are often used as entrainers. However, environmental influence and high energy-consumption are significant problems in industrial application. In this study, a systematic screening strategy and innovative energy-saving design for ionic liquid-based extractive distillation process was proposed. The innovative energy-saving design focused on the binary minimum azeotrope mixtures isopropanol and water. Miscibility, environmental impact and physical properties (e.g., melting point and viscosity) of 30 ionic liquids were investigated. 1-Ethyl-3-methyl-imidazolium dicyanamide and 1-butyl-3-methyl-imidazolium dicyanamide were selected as candidate entrainers. Feasibility analysis of these two ionic liquids was further performed via residue curve maps, isovolatility line and temperature profiles. An innovative ionic liquid-based extractive distillation process combining distillation column and stripping column was designed and optimized with the objective function of minimizing the total annualized cost. The results demonstrate that the total annualized cost was reduced by 19.9% with 1-ethyl-3-methyl-imidazolium dicyanamide as the entrainer and by 24.3% with 1-butyl-3-methyl-imidazolium dicyanamide, compared with that of dimethyl sulfoxide. The method proposed in this study is conducive to the green and sustainable development of extractive distillation process.

关键词： ionic liquid     entrainer screening     feasibility analysis     extractive distillation    

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Progress in membrane distillation crystallization: Process models, crystallization control and innovative

Xiaobin Jiang, Linghan Tuo, Dapeng Lu, Baohong Hou, Wei Chen, Gaohong He

《化学科学与工程前沿（英文）》 2017年 第11卷 第4期   页码 647-662 doi: 10.1007/s11705-017-1649-8

摘要： Membrane distillation crystallization (MDC) is a promising hybrid separation process that has been applied to seawater desalination, brine treatment and wastewater recovery. In recent years, great progress has been made in MDC technologies including the promotion of nucleation and better control of crystallization and crystal size distribution. These advances are useful for the accurate control of the degree of supersaturation and for the control of the nucleation kinetic processes. This review focuses on the development of MDC process models and on crystallization control strategies. In addition, the most important innovative applications of MDC in the last five years in crystal engineering and pharmaceutical manufacturing are summarized.

关键词： membrane distillation crystallization     mathematics model     nucleation     separation     hybrid process    

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Combining extractive heterogeneous-azeotropic distillation and hydrophilic pervaporation for enhanced

Eniko Haaz, Botond Szilagyi, Daniel Fozer, Andras Jozsef Toth

《化学科学与工程前沿（英文）》 2020年 第14卷 第5期   页码 913-927 doi: 10.1007/s11705-019-1877-1

摘要： The separation of non-ideal mixtures using distillation can be an extremely complex process and there continues to be a need to further improve these techniques. A new method which combines extractive heterogeneous-azeotropic distillation (EHAD) and hydrophilic pervaporation (HPV) for the separation of non-ideal ternary mixtures is demonstrated. This improved distillation method combines the benefits of heterogeneous-azeotropic and extractive distillations in one column but no added materials are needed as is usually the case with pervaporation. The separation of water-methanol-ethyl acetate and water-methanol-isopropyl acetate mixtures were investigated to demonstrate the accuracy of the combined EHAD/HPV technique. There is not currently an established treatment strategy for the separation of the second mixtures in the literature. These separation processes were rigorously modelled and optimized using a professional flowsheet. The objective functions were total cost and energy consumption and heat integration was also investigated. The verification of the process modelling was carried out using laboratory-scale measurements. Extractive heterogeneous-distillation combined with methanol dehydration was found to be more efficient than conventional distillation for the separation of these highly non-ideal mixtures.

关键词： hydrophilic pervaporation     non-ideal mixture     modelling     extractive heterogeneous-azeotropic distillation     heat integration    

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冷风闪速冶金在中国的实现和发展

张文海

《中国工程科学》 2002年 第4卷 第11期   页码 19-25

摘要：

基于常温变量喷射—动力波洗涤闪速炼铜技术，介绍了“冷风闪速冶金”等6项创新技术在金隆铜业公司的实施和实现清洁生产的业绩，并就我国铜、镍闪速冶金技术提出了近期的研究方向。

关键词： 铜冶金     闪速熔炼     冷风冶炼     动力波洗涤     中国    

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标题 作者 时间 类型 操作

Simulation analysis of methanol flash distillation circulation process in biodiesel production with supercritical

Zhengjiao TANG, Cunwen WANG, Weiguo WANG, Jia GUO, Yuanxin WU, Jinfang CHEN, Yigang DING

期刊论文

A novel method for generating distillation configurations

Hongzhe Hou, Yiqing Luo

期刊论文

Phase change effect of low melting point metal for an automatic cooling of USB flash memory

Haoshan GE, Jing LIU

期刊论文

Synthesis of hydrophobic carbon nanotubes/reduced graphene oxide composite films by flash light irradiation

Kai Wang, Jinbo Pang, Liwei Li, Shengzhe Zhou, Yuhao Li, Tiezhu Zhang

期刊论文

A review on membrane distillation in process engineering: design and exergy equations, materials and

期刊论文

The use of carbon nanomaterials in membrane distillation membranes: a review

Sebastian Leaper, Ahmed Abdel-Karim, Patricia Gorgojo

期刊论文

Design and optimization of reactive distillation: a review

期刊论文

闪速熔炼——清洁高效的炼铜工艺

周松林

期刊论文

Methyl acetate–methanol mixture separation by extractive distillation: Economic aspects

Elena Graczová, Branislav Šulgan, Samuel Barabas, Pavol Steltenpohl

期刊论文

CFD simulation on membrane distillation of NaCl solution

Zhaoguang XU, Yanqiu PAN, Yalan YU

期刊论文

Prediction of the flash points of alkanes by group bond contribution method using artificial neural networks

PAN Yong, JIANG Juncheng, WANG Zhirong

期刊论文

Systematic screening procedure and innovative energy-saving design for ionic liquid-based extractive distillation

期刊论文

Progress in membrane distillation crystallization: Process models, crystallization control and innovative

Xiaobin Jiang, Linghan Tuo, Dapeng Lu, Baohong Hou, Wei Chen, Gaohong He

期刊论文

Combining extractive heterogeneous-azeotropic distillation and hydrophilic pervaporation for enhanced

Eniko Haaz, Botond Szilagyi, Daniel Fozer, Andras Jozsef Toth

期刊论文

冷风闪速冶金在中国的实现和发展

张文海

期刊论文